Vigilancia Tecnológica

Molecular design and properties of intrinsic flame retardant P?N?B co?acting epoxy resin.AbstractCurrently, epoxy resin (EP) is widely used in various fields, but its flammability greatly limits the wider application of EP. In recent years, additive flame retardants have been widely used to enhance the flame retardancy of EPs, but poor resistance to weather and aging is a prevalent issue encountered with additive flame retardants. To improve the weather fastness, researchers have successfully created and synthesized EP molecules that possess a combined effect of P, N, and B. The results demonstrate a significant enhancement in the mechanical properties of materials containing 20% BVN/10% VPD/EP compared with those of pure EP. 20% BVN/20% VPD/EP exhibited a vertical combustion rating of V?1 with a limiting oxygen index measuring at 29.8%. The flame retardant epoxy thermosets exhibited a notable decrease in both the maximum heat release rate and total heat release. The findings indicate that the inherent flame?retardant properties of the P?N?B coacting EP are not only characterized by exceptional curing and flame retardancy but also by superior resistance to weathering and aging compared with the additive flame retardant.