Vigilancia Tecnológica

The distribution of spray?dried cellulose nanocrystal particles in polypropylene can be probed by water absorption and the crystallization behaviors of the composites.AbstractUnderstanding the percolation threshold is essential for determining the performance of particle?reinforced polymer composites. Spray?dried cellulose nanocrystals (SDCNC) of micrometer size reinforced homopolymer polypropylene (HPP) composites at 20, 30, 40, and 50?wt.% were prepared to investigate the percolation threshold of SDCNC particles in HPP. The effect of a compatibilizer (maleic anhydride polypropylene (MAPP)) at 3, 5, and 7?wt.%, on the SDCNC percolation networks and composites performance were also studied. The results indicated that SDCNC particle percolation networks in HPP were established between 30 and40?wt.%. For composites without MAPP, the impact strength significantly increased by up to 23% below the percolation threshold and declined beyond it. The peak crystallization temperature of HPP was steadily increased until 30?wt.% SDCNC particles were added due to the SDCNC saturated nucleation function at the threshold. Introducing MAPP significantly improved tensile strength (58%), tensile strain (61%), flexural strength (45%), and impact strength (91%) compared with the corresponding composites without MAPP, attributed to the enhanced interfacial adhesion between the SDCNC particles and HPP. Water absorption results indicated that adding MAPP changed the SDCNC particle distribution networks within the matrix above the percolation threshold but did not change it below the threshold.