Vigilancia Tecnológica

Vacuum injection molding and mechanical properties of composites.In recent years, the growing environmental awareness has prompted increased attention towards the substitution of nonrecyclable thermosetting epoxy resin composite materials with recyclable thermoplastic composite materials. The objective of this study is to utilize a laboratory?made polymethyl methacrylate (PMMA)/methyl methacrylate (MMA) binary liquid resin (PMBLR) to prepare thermoplastic resin/glass fiber (GF) composite materials using the vacuum?assisted perfusion method. These composites are then compared with GF?reinforced thermosetting epoxy resin composites. The investigation reveals a significant influence of benzoyl peroxide (BPO) content on the mechanical properties of pure MMA and PMBLR casting resins, which also incorporate N?methyl?N?((1?methyl?1H?indol?3?yl) methyl) aniline (DMA) as redox composite initiators. The optimal mechanical properties for both types of casting resins are achieved at a DMA:BPO:MMA ratio of 0.5:1.2:100. Additionally, at a PMMA concentration of 24?wt% in PMBLR under this specific initiator ratio, the composites demonstrate the most desirable properties. Furthermore, a comparative analysis of PMBLR/GF composites and epoxy/GF composites indicates that the former exhibit superior 90° tensile strength, bending strength, and short beam shear strength. The fracture morphology analysis highlights discernible micro?ductile fracture characteristics in PMBLR/GF composites, distinguishing them from epoxy/GF composites. Dynamic thermomechanical analysis (DMA) results further reveal a higher storage modulus and loss factor in PMBLR/GF composites when compared to epoxy/GF composites.HighlightsGlass fiber?reinforced composites were fabricated at ambient temperature.A degradable PMMA/MMA binary thermoplastic resin (PMBLR) was developed as a replacement for non?degradable epoxy.PMBLR composites exhibit enhanced strength compared to epoxy: tensile (+18.8%), bending (+27.4%), and short beam shear (+34.3%).