Vigilancia Tecnológica

The combination of layer?by?layer assembly and grazing incidence spraying is used to fabricate organized nanocellulose?based structures with nanoscale controlled helicoidal arrangement of cellulose nanofibrils. Experimental results demonstrate that this additive manufacturing approach allows for high tunability in layer composition and structure, resulting in nanocomposite films with complex controlled internal structures and tailored chiroptical properties.Cellulose?based nanocomposites are highly appealing for the development of next?generation sustainable functional materials. Although many advances have been made in this direction, the true potential of fibrillar nanocomposites has yet to be realized because available fabrication approaches are inadequate for achieving precise structural control at the sub?micrometer scale. Here a spray?assisted alignment methodology of cellulose nanofibrils is combined with the layer?by?layer assembly into an additive manufacturing process in which the alignment direction of each cellulose layer is rationally selected to achieve thin films with a helicoidal arrangement of the nanofibrils. The helicoidal structure of the films is verified by measuring the circular dichroism (CD) of the samples. The sign and position of the structural CD peak show that the handedness and the pitch of the chiral structures can be easily tuned by deliberately selecting simple parameters, such as the number of consecutive cellulose layers sprayed in the same direction, and the angle of rotation between successive stacks of layers. To the authors’ knowledge, this approach is unique as it offers the possibility to prepare complex nanocomposite architectures with various nanoscale?controlled sub?structures from different anisometric objects, which is enabling novel designs of composite films with damage?resistant and/or optical filtering functionalities.