Vigilancia Tecnológica

Rechargeable and flexible aqueous batteries (ABs) have emerged as one of promising energy devices which is primarily due to the safety, environmental friendliness and economic efficiency. However, because of the freezing behavior of aqueous electrolytes, most ABs possess poor performance when the working temperature drops below zero. To solve this problem, a gel polymer electrolyte (GPE) with high ionic conductivity (IC) and frost?resistance is designed for aqueous Zn?Li hybrid batteries by a biomass?based polymers complex consisting of carboxyl modified sodium alginate (SA) and zwitterionic betaine (BA). Introducing iminodiacetic acid to enrich ?COOH groups along the SA main chains could improve IC of the prepared GPEs to 41.27 and 20.96 mS cm?1 at 20 and ?20 oC, respectively. At ?20 oC, the discharge capacity of the resultant cell is two times higher than that of the liquid electrolyte?based cell, and the cell presents a capacity retention of 91.6% after 300 charge/discharge cycles at 1 C. This proposed strategy greatly improve the IC of GPEs at freezing temperature, which is expected to broaden the practical application of GPEs in wide range of temperature.