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Plasma Functionalization for Enhanced Natural Dye Affinity on Bioplastics: A Novel Approach

This study embarks on the innovative use of glow discharge plasma technology to enhance the surface properties of cassava starch?based bioplastics, making them more compatible With natural dyes. by optimizing plasma treatment conditions, dye retention was improved, contributing to the development of green printing processes and eco?friendly materials.ABSTRACTBioplastics offer biodegradability and reduced environmental impact but often use nondegradable synthetic dyes. This study introduces a novel application of glow discharge plasma (GDP) technology to modify cassava starch?based bioplastic sheets, specifically optimizing conditions to enhance their hydrophilicity and adhesion for natural dyes. This research systematically tailors plasma treatment parameters to maximize the interaction between bioplastics and eco?friendly natural dyes. Optimal conditions, identified as 30?W for 3?min using oxygen, air, and nitrogen plasma treatments, demonstrate significant advancement in sustainable material development. Analyses (ATR?FTIR, EDX, XPS) showed increased concentration of polar functional groups and oxygen content, with FE?SEM and water contact angle measurements revealing improved surface roughness and wettability, respectively. Oxygen plasma treatment yielded the highest hydrophilicity and crystallinity of the polymer. Tensile tests indicated increased strength and decreased elongation. UV?Vis spectroscopy confirmed enhanced dye retention and reduced leaching. This study demonstrates GDP's potential to incorporate eco?friendly natural dyes into bioplastics, thereby contributing to the development of more sustainable materials.


Fecha publicación: 2024/10/17

Autor: Faizatin Liyan Syibyan, Dwi Siswanta, Bidhari Pidhatika, Suprapto, Yuichi Kamiya, Ryoichi Otomo

Plasma Processes and Polymers

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