Vigilancia Tecnológica

This study aims to enhance CO2/CH4 separation using cellulose acetate and polyetherimide membranes filled with graphene (GR) and acid?treated GR. The 0.1% acid?treated GR/cellulose acetate (43?Barrers, 14.80 selectivity) and 0.5% GR/polyetherimide membranes (17.48?Barrers, 8.96 selectivity) have shown the best gas permeation results.Gas separation membranes are crucial for upgrading biogas by separating carbon dioxide (CO2) from biogas, thereby enhancing its calorific value and reducing greenhouse gas emissions. This study aims to improve CO2/CH4 separation using mixed?matrix membranes (MMMs) by incorporating graphene (Gr) and acid?treated graphene (AGr) fillers in a cellulose acetate (CA) polymer matrix. Similarly, polyetherimide (PEI) MMMs were also prepared with Gr and AGr fillers to draw a comparison. Various characterization techniques, including Fourier transform infrared spectroscopy, differential scanning calorimetry, field emission scanning electron microscopy, Raman spectroscopy, and X?ray diffraction, were employed to investigate the structural and morphological properties of the membranes and fillers. Gas permeation tests using a model biogas mixture (40% CO2 and 60% CH4) revealed that the 0.1%AGr/CA membrane achieved the highest CO2 permeability of 43?Barrers, which is approximately 307% more than that of the pure CA membrane, and showed a CO2/CH4 selectivity of 14.80. The 0.5%Gr/PEI membrane demonstrated the best performance among PEI?based MMMs, with a CO2 permeability of 17.48?Barrers and a CO2/CH4 selectivity of 8.96. These results indicate that the incorporation of Gr and AGr significantly enhances the gas separation performance over pure CA and PEI membranes.HighlightsGraphene (G) and acid?treated Gr?based cellulose acetate (CA) and polyetherimide (PEI) mixed?matrix membranes (MMMs) were fabricated.Model biogas was used for testing CO2 and CH4 gas permeation.The 0.1% AGr/CA MMM showed 307% higher CO2 permeability than pure CA.The 0.5% Gr/PEI MMM showed 435% higher CO2 permeabilit than pure PEI.Structural properties were confirmed by Fourier transform infrared spectroscopy, differential scanning calorimetry, field emission scanning electron microscopy, Raman, and X?ray diffraction.