Vigilancia Tecnológica

A polymethacrylate comprising chitin?derived 2?acetamide?2?deoxyisosorbide (ADI) as a repeat unit is developed as a new biobased high?performance polymer. The UV–visible spectrum of the polymer indicates high transparency at 400–650?nm. DSC analysis suggests that the polymer shows high Tg at 168?°C, similar to those of isosorbide?based polymethacrylates.Synthesis and applications of biobased polymers have been extensively studied in order to reduce the use of petroleum?based polymers and likewise environmental load. Several biobased polymers have been produced on a commercial large scale to date. However, the lineup of biobased high?performance polymers with transparency and high glass transition temperature is inadequate and their development is a critical issue. In this article, we design a new biobased polymethacrylate comprising rigid cis?fused bicyclic 2?acetamide?2?deoxyisosorbide (ADI) as a repeat unit. We have recently invented catalytic transformation systems from chitin as a marine biomass to ADI as a new nitrogen?containing platform chemical. The ADI?based polymethacrylate is synthesized via free radical polymerization of the methacrylic acid ester of ADI initiated by (NH4)2S2O8 and N,N,N?,N??tetramethylethylenediamine in dimethylsulfoxide–H2O mixed solvent. The molecular weight and its dispersity are estimated by size exclusion chromatography on the basis of polymethylmethacrylate standards. UV–visible spectroscopy demonstrates the high transparency of the polymer in the visible wavelength region. Differential scanning calorimetry analysis of the polymer clarifies the remarkably high glass transition temperature, compared with that of polymethylmethacrylate. The thermal decomposition temperature of the polymer is also evaluated by thermogravimetric analysis. On the basis of the favorable properties of the ADI?based polymer, the present study proposes it as a nitrogen?containing biobased polymer useful for real?world applications. © 2024 Society of Chemical Industry.